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PCB HASL and Lead-Free HASL Processes

PCB HASL and Lead-Free HASL Processes

HASL process

HASL (Hot Air Solder Leveling) is one of the most classic and cost-effective surface treatment processes in PCB manufacturing and plays an important role in the electronics manufacturing industry. This process involves covering the copper surface with a tin-lead alloy layer to provide reliable soldering performance and oxidation protection for PCBs.

HASL process

1.1 Differences between HASL and lead-free HASL

HASL (Hot Air Solder Leveling) is one of the most classic and cost-effective surface treatment technologies in PCB-productie. This process coats copper surfaces with a tin-lead alloy layer to provide reliable solderability and oxidation resistance. With increasing environmental requirements, lead-free HASL has become the industry standard.

Material Composition Differences:

  • Traditional HASL uses Sn63/Pb37 alloy (63% tin + 37% lead), melting point: 183°C
  • Lead-free HASL primarily uses:
  • SAC305 (96.5% tin + 3% silver + 0.5% copper), melting point: 217-220°C
  • SnCu0.7 (99.3% tin + 0.7% copper), melting point: 227°C
  • Pure tin (Sn100), melting point: 232°C

Process Characteristics Comparison:

PropertyLeaded HASLLead-Free HASL
Melting Point183°C217-232°C
Solder Pot Temp200-210°C240-255°C
Afwerking oppervlakBrightRelatively Dull
Mechanische sterkteGood Ductility (High Impact Resistance)Hard but Brittle
WettabilityExcellent (Contact Angle <30°)Good (Contact Angle 35-45°)
Environmental ComplianceContains Lead (37%)Lead Content <0.1% (RoHS Compliant)
KostenOnder15-20% Higher
ApplicabilityGeneral PurposeRequires Higher Solder Temps

Practical Performance Differences:

  • Soldeerbaarheid:
  • Leaded HASL offers better solder activity with shorter wetting time (1-2 sec)
  • Lead-free HASL requires stronger flux and tighter temperature control
  • Betrouwbaarheid:
  • Leaded solder joints exhibit better thermal fatigue resistance (more temperature cycles)
  • Lead-free solder joints maintain higher mechanical strength after long-term aging
  • Process Window:
  • Leaded HASL has a wider process window (±10°C)
  • Lead-free HASL requires tighter temperature control (±3°C)

Professional Tip: Topfast optimizes lead-free HASL parameters to achieve >99.5% soldering yield while meeting IPC-6012 Class 3 standards.

1.2 Core HASL Process Flow

As a professional PCB manufacturer, Topfast employs fully automated HASL production lines with strict standardized processes:

1.2.1 Pre-Treatment Stage

  • Chemical Cleaning:
  • Acid cleaner (pH 2-3) removes copper oxides
  • Temperature control: 40-50°C, duration: 2-3 min
  • Micro-etching ensures surface roughness Ra 0.3-0.5μm
  • Rinsing:
  • Three-stage countercurrent rinsing (DI water resistivity >15MΩ·cm)
  • Hot air drying (60-80°C)

1.2.2 Flux Application

  • Application Methods:
  • Foaming (traditional): Flux thickness 0.01-0.03mm
  • Spray (advanced): More uniform, 30% less flux consumption
  • Flux Types:
  • No-clean rosin-based (ROH)
  • Solid content: 8-12%, acid value: 35-45mgKOH/g

1.2.3 Hot Air Leveling Key Steps

  • Preheating:
  • Leaded: 130-140°C
  • Lead-free: 150-160°C
  • Duration: 60-90 sec
  • Solder Dipping:
  • Solder pot temperature:
    • Leaded: 210±5°C
    • Lead-free: 250±5°C
  • Dwell time: 2-4 sec (±0.5 sec precision)
  • Immersion depth: 3-5mm
  • Hot Air Leveling:
  • Air knife parameters:
    • Pressure: 0.3-0.5MPa
    • Temperature: 300-350°C
    • Angle: 4° downward tilt
    • Air velocity: 20-30m/s
  • Processing time: 1-2 sec
  • Cooling:
  • Forced air cooling (rate: 2-3°C/sec)
  • Final temperature <60°C

1.2.4 Quality Inspection

  • Online AOI (100% coverage):
  • Solder thickness inspection (1-40μm)
  • Surface defect detection (solder balls, exposed copper, etc.)
  • Sampling Tests:
  • Solderability test (245°C, 3 sec)
  • Adhesion test (tape method)

Technological Breakthrough: Topfast’s nitrogen-protected lead-free HASL process reduces solder oxidation from 5% to <1.5%, significantly improving soldering yield.

1.3 Process Advantages and Limitations

Voordelen

  • Kostenefficiëntie:
  • Low equipment investment (~1/3 of ENIG)
  • Significant material cost savings (40-60% cheaper than ENIG)
  • Solder Reliability:
  • Withstands >3 reflow cycles (peak 260°C)
  • High joint tensile strength (leaded: 50-60MPa; lead-free: 55-65MPa)
  • Wide Applicability:
  • Suitable for various pad sizes (min. 0.5mm pitch)
  • Compatible with through-hole and SMT processes
  • Storage Performance:
  • 12-month shelf life (RH <60%)
  • Excellent oxidation resistance (48-hour salt spray test)

Beperkingen

  • Fine-Pitch Restrictions:
  • Not suitable for <0.4mm pitch BGA/QFN components
  • Solder bridging risk for fine-pitch designs
  • Planarity Issues:
  • Surface unevenness: 15-25μm (affects HDI assembly)
  • Thickness variation up to 20μm between large/small pads
  • Thermal Stress:
  • High-temp process (especially lead-free) may affect high-Tg materials
  • Higher warpage risk for thin boards (<0.8mm)
  • Environmental Considerations:
  • Leaded HASL non-RoHS compliant
  • Lead-free HASL consumes more energy (30-50°C higher temperatures)

Need professional HASL support? Contact Topfast engineers voor oplossingen op maat

HASL process

ENIG (Electroless Nickel Immersion Gold) Process

2.1 Process Principles

ENIG forms a composite protective layer through electroless nickel plating and immersion gold:

  • Nickel layer: 3-6μm (7-9% phosphorus)
  • Gold layer: 0.05-0.1μm

Belangrijkste parameters:

  • Nickel bath temp: 85-90°C
  • Plating rate: 15-20μm/h
  • Gold bath temp: 80-85°C
  • pH: Nickel bath 4.5-5.0, Gold bath 5.5-6.5

2.2 Advantages

  • Superb Flatness (Ra<0.1μm):
  • Ideal for <0.3mm pitch BGA/CSP
  • Pad coplanarity <5μm/m
  • Oxidation Resistance:
  • 18-month shelf life
  • J-STD-003B Class 3 certified
  • Electrical Conductivity:
  • Gold resistivity: 2.44μΩ·cm
  • Contact resistance <10mΩ

2.3 Challenges

  • Black Pad Issue:
  • Causes: Nickel over-etching or abnormal phosphorus content
  • Solution: Topfast’s patented passivation reduces black pad rate to <0.1%
  • Cost Factors:
  • High material costs (gold price volatility)
  • Complex process (8-10 steps)
  • Solder Joint Strength:
  • Brittle Ni-Au IMC layer
  • Tensile strength ~40-45MPa

Topfast’s ENIG achieves ±10% thickness uniformity, surpassing industry ±15% standards.

OSP (organisch soldeerbaarheidsbewaarmiddel)

3.1 Process Principles

OSP forms a 0.2-0.5μm organic protective film on bare copper, containing:

  • Benzotriazole compounds
  • Imidazole compounds
  • Carboxylic acids

Processtroom:

  1. Acid clean (5% H2SO4, 2min)
  2. Micro-etch (Na2S2O8, remove 1-2μm copper)
  3. OSP treatment (40-50°C, 1-2min)
  4. Drying (60-80°C hot air)

3.2 Advantages

  • Kosteneffectief:
  • 60% cheaper than HASL
  • Low equipment investment (~1/5 of ENIG)
  • Signaalintegriteit:
  • Stable dielectric constant (ΔDk <0.02)
  • Ideal for high-frequency applications (>10GHz)
  • Eco-Friendly:
  • No heavy metals
  • Simplified wastewater treatment

3.3 Limitations

  • Solderability Window:
  • Must use within 24 hours of opening
  • Only suitable for 1 reflow cycle (yield drops 30% for second reflow)
  • Inspection Difficulties:
  • Hard to measure film thickness optically
  • Requires special ICT treatment
  • Storage Conditions:
  • Vacuum packaging required (RH <30%)
  • Storage temp: 15-30°C

Topfast’s enhanced OSP extends shelf life from 3 to 6 months and withstands 2 reflow cycles.

HASL process

Process Selection Guide

4.1 Comparison

ParameterHASLENIGOSP
Kosten$$$$$
Flatness△ (15-25μm)◎ (<5μm)○ (<10μm)
Soldeerbaarheid◎ (3 reflows)○ (5 reflows)△ (1-2 reflows)
Houdbaarheid12mo18mo6mo
Min. Pitch>0.5mm>0.3mm>0.4mm
Eco-FriendlyLead-free OKUitstekendUitstekend
ToepassingenConsumentenelektronicaHigh-Density ICsQuick-Turn

4.2 Recommendations

  • Consumentenelektronica:
  • Lead-free HASL (best cost-performance)
  • Control solder paste volume for fine-pitch components
  • ENIG (superior flatness)
  • Strict nickel quality control
  • OSP/ENIG (better signal integrity)
  • Avoid HASL’s uneven surface
  • Prototyping:
  • OSP (fastest turnaround)
  • Ensure timely assembly

4.3 Topfast Capabilities

Complete surface finish solutions:

  • 20 automated HASL lines (500,000㎡/month)
  • 10 ENIG lines (±8% thickness uniformity)
  • 5 OSP lines (nano-enhanced available)
  • 100% inline inspection (AOI+SPI)

Download PCB Surface Finish Selection Guide